2-[(5-Chloro-2-oxidobenzylidene)azaniumyl]-2-methylpropane-1,3-diol
2-[(5-Chloro-2-oxidobenzylidene)azaniumyl]-2-methylpropane-1,3-diol
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The title compound, C11H14ClNO3, Canes was prepared by the condensation of equimolar quantities of 5-chlorosalicylaldehyde and 2-amino-2-methylpropane-1,3-diol in methanol.In the crystal, it exists in the zwitterionic form, with nominal proton transfer from the phenol group to the imine N atom.This results in the formation of an intramolecular N—H.
O hydrogen bond, which generates an S(6) ring.Intermolecular O—H.O LIQUID MAGNESIUM hydrogen bonds arise from the hydroxy groups, forming (001) sheets.